Orders with Payment Methods Account and Other will fall into the Awaiting Invoice page of the Invoice Module.

Orders can only have Payment Method Account if that option has been enabled in the related Customer Detail TAB.

Payment Method Other can be chosen in the Back Office system and will have the Credit Terms associated with the Other Box in Setup > Organization > Invoice.

The only other time, when Other applies is if there is no Payment gateway integration setup and a Customer orders online (but does not select On Account or it is not available to them).

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